Combustion characteristics and kinetics of DPR Korea’s anthracite in O2/N2 and O2/CO2 atmosphere

Journal of Thermal Analysis and Calorimetry - In O2/N2 and O2/CO2 atmospheres with oxygen concentrations of 21%, 30%, and 50%, combustion characteristics index, apparent activation energy, and...     

System scan of the multiplicity correlation between forward and backward rapidities in relativistic heavy-ion collisions using a multi-phase transport model

A systematic study on forward–backward (FB) multiplicity correlations from large systems to small ones through a multi-phase transport model (AMPT) has been performed and the phenomenon that correlation strength increases with centrality can be explained by taking the distribution of events as the superposition of a series of Gaussian distributions. It is also found that correlations in the \begin{document}$ \eta -\phi $\end{document} plane can imply the shape of the event. Furthermore, long-range correlations originate from the fluctuations associated with the source information. FB correlations allow us to decouple long-range correlations from short-range correlations, and may provide a chance to investigate the α-clustering structure in initial colliding light nuclei as well. It seems the tetrahedron ¹⁶O + ¹⁶O collision gives a more uniform and symmetrical fireball, that emits the final particles more isotropically or independently in the longitudinal direction, indicating that the forward–backward multiplicity correlation could be used to identify the pattern of α-clustered ¹⁶O in future experiments.     

Classify the Higgs decays with the PFN and ParticleNet at electron–positron colliders

Various Higgs factories are proposed to study the Higgs boson precisely and systematically in a model- independent way. In this study, the Particle Flow Network and ParticleNet techniques are used to classify the Higgs decays into multicategories, and the ultimate goal is to realize an "end-to-end" analysis. A Monte Carlo simulation study is performed to demonstrate the feasibility, and the performance looks rather promising. This result could be the basis of a "one-stop" analysis to measure all the branching fractions of the Higgs decays simultaneously.     

基于无人机探测大柴旦地区近地层气溶胶特征

通过改装多旋翼无人机（UAV）和搭载各类载荷以及联合地基观测设备对大柴旦地区大气、环境以及气溶胶参数进行测量。利用获得的数据资料，对该地区近地层气溶胶粒子数浓度（即单位体积空气中气溶胶粒子的数目）、消光系数以及气象要素等特征进行了分析。结果表明，在大柴旦地区，近地层气溶胶粒子数浓度日变化显著，呈现双峰形态，气溶胶粒子数浓度的变化范围为75～220 cm^-3,消光系数的变化范围为0.004～0.038 km^-1;当风速小于6 m/s时，气溶胶粒子数浓度与风速呈负相关关系；当风速大于6 m/s时，二者呈正相关关系；相对湿度对气溶胶粒子的影响较小，这可能是由于该地区以沙尘型气溶胶为主，吸湿性较弱。本研究基于多旋翼无人机探测平台，可以有效地获得近地层精细化大气、环境结构，有助于研究人员了解该地区气溶胶的结构、变化特征以及建立气溶胶模式，同时也为气溶胶及大气环境参数探测方法提供了技术支撑及思路拓展。     

Artematrovirenolides A—D and Artematrolides S—Z,Sesquiterpenoid Dimers with Cytotoxicity against Three Hepatoma Cell Lines from Artemisia atrovirens

Inspired by the intriguing structures and remarkable activities of sesquiterpenoid dimers,12 new sesquiterpenoid dimers,artematrovirenolides A—D(1—4)and artematrolides S—Z(8—12),were isolated from the EtOAc fraction of Artemisia atrovirens through a bioactivity-guided approach.Their structures were elucidated by comprehensive spectroscopic data and absolute configuration was assigned based on single crystal X-ray diffraction data and ECD calculations.Structurally,all compounds are presumably formed via[4+2]cycloaddition involving three connecting model.Compounds 1—4 are four novel hetero-dimeric[4+2]Diels-Alder adducts dimerized from a rotundane-type unit and a guaiane-type monomer,and compounds 5—12 are eight new homo-dimeric[4+2]adducts derived from two guaianolide moieties.A putative biosynthetic pathway for compounds 1—4 was also proposed.Compounds 4,6,7,and 10 demonstrated moderate cytotoxicity against HepG2,SMMC-7721,and Huh7 cell lines with IC50 values ranging from 9.3 to 62.3μmol/L.Interestingly,compounds 5 and 11 manifested cytotoxicity with IC50 values of 13.6 and 12.8(HepG2),18.5 and 13.1(SMMC-7721),and 16.5 and 19.4μmol/L(Huh7),respectively,which were equivalent to the positive control,sorafenib.This investigation suggests that compounds 5 and 11 might be considered as potent antihepatoma candidates and deserve further structural modification and mechanism study.     

The induction of PANoptosis in KRAS-mutant pancreatic ductal adenocarcinoma cells by a multispecific platinum complex

Science China Chemistry - Oncogenic KRAS reprograms pancreatic ductal adenocarcinoma (PDAC) cells to a state that is awfully resistant to apoptosis. An alternative coping strategy is to trigger a...     

Unconditionally optimal convergence of an energy-conserving and linearly implicit scheme for nonlinear wave equations

In this paper, we present and analyze an energy-conserving and linearly implicit scheme for solving the nonlinear wave equations. Optimal error estimates in time and superconvergent error estimates in space are established without certain time-step restrictions. The key is to estimate directly the solution bounds in the H²-norm for both the nonlinear wave equation and the corresponding fully discrete scheme, while the previous investigations rely on the temporal-spatial error splitting approach. Numerical examples are presented to confirm energy-conserving properties, unconditional convergence and optimal error estimates, respectively, of the proposed fully discrete schemes.

     

Synthesis of Diarylmethanes via Pd-Catalyzed Coupling of Aryltosylates with Benzyltitanium Reagents

Russian Journal of General Chemistry - Two new bidentate phosphate ligands have been synthesized by Pd-catalyzed coupling reactions, characterized and evaluated. An efficient and simple...     

Polyvinylpyrrolidone and graphene-modified hematite nanoparticles for efficient electrocatalytic oxidation of p-nitrophenol

Journal of Solid State Electrochemistry - Polyvinylpyrrolidone (PVP) and graphene (G)-modified iron oxides (Fe2O3-PVP-G) are prepared by a simple hydrothermal reaction. Their morphology and...